Use WinRAR or 7-Zip to extract the EDIT.bin file from the downloaded .rar archive.
This file is generally compatible with the "NSP" patch series, but it can often work with the vanilla game or other similar patches (though results may vary with player faces and kits). Download PES 2013 NEW OPTION FILE NSP 2023 rar
Go to your Documents\KONAMI\Pro Evolution Soccer 2013\save folder and move your old EDIT.bin to a safe place. Replace: Copy the new EDIT.bin into that same save folder. Play: Launch the game and enjoy the 2023 rosters! Use WinRAR or 7-Zip to extract the EDIT